List of Superconductors and How They Work
Introduction
Superconductivity is a fascinating phenomenon in physics where certain materials, when cooled below a critical temperature, exhibit zero electrical resistance and the expulsion of magnetic fields. This makes them essential in various applications, including medical imaging, energy storage, and transportation. Let’s discuss how superconductors work using ten examples of superconducting materials.
How Superconductors Work
Superconductivity occurs when a material’s electrons pair up to form what is known as Cooper pairs. These pairs move through the material without scattering, which is what causes electrical resistance. In normal conductors like copper or aluminum, electrons experience resistance as they collide with atoms, resulting in energy loss. However, in superconductors, once the material is cooled below a critical temperature, this phenomenon of resistance-free current flow occurs, enabling energy to move without loss.
At the quantum level, superconductivity is explained by the BCS theory (Bardeen, Cooper, and Schrieffer). This theory describes how the interaction between electrons and vibrations in the crystal lattice leads to the formation of Cooper pairs. These pairs move collectively, without scattering, making the material capable of conducting electricity without any energy dissipation.
Superconductor Properties
Superconductors have a unique set of properties that make them stand out from other materials:
Figure 1 Critical Temperature of Superconductors[1]
- Zero Electrical Resistance: The most significant property of superconductors is that they allow electricity to flow without any resistance, which eliminates energy loss during transmission.
- Meissner Effect: Superconductors exhibit the Meissner effect, where they expel magnetic fields from their interior when they transition into the superconducting state. This phenomenon allows for applications like magnetic levitation.
- Critical Temperature (Tc): Each superconductor has a specific critical temperature below which it exhibits superconductivity. This temperature varies depending on the material. For example, some high-temperature superconductors have critical temperatures above the boiling point of liquid nitrogen (-196°C).
- Quantum Levitation: Superconductors can levitate above magnets due to the interaction between the superconductor’s expulsion of magnetic fields and the field generated by the magnet. This principle is utilized in technologies like maglev trains.
- High Current Carrying Capacity: Superconductors can carry much higher electrical currents than conventional conductors, which makes them ideal for use in high-energy applications like particle accelerators.
10 Examples of Superconductors
[2]
- Niobium (Nb) Niobium is one of the most commonly used superconductors due to its relatively high critical temperature of 9.25 K and its ease of use in practical applications such as MRI machines and particle accelerators.
- Yttrium Barium Copper Oxide (YBCO) YBCO is a high-temperature superconductor with a critical temperature of around 93 K, making it ideal for applications in the power industry, including power cables and magnetic shields.
- Magnesium Diboride (MgB2) Magnesium Diboride, with a critical temperature of 39 K, is a relatively inexpensive superconductor. It has applications in electronics, energy storage, and MRI technology.
- Lead (Pb) Lead was one of the first materials discovered to exhibit superconductivity. Its critical temperature is 7.2 K, and it’s used in various scientific experiments and applications requiring low temperatures.
- Bismuth Strontium Calcium Copper Oxide (BSCCO) BSCCO is another high-temperature superconductor, with a critical temperature of around 108 K. It is used in power cables, magnets, and other electrical devices.
- Iron-Based Superconductors Iron-based superconductors, a relatively new class discovered in 2008, are known for their high critical temperatures and potential in electronics and energy applications.
- Tungsten (W) Tungsten is a high-density material that exhibits superconductivity at very low temperatures, making it useful in certain niche applications, including high-field magnets.
- Vanadium Gallium (V3Ga) Vanadium Gallium is a superconductor with a relatively high critical temperature of 13.8 K. It is used in applications that require both superconductivity and high magnetic fields.
- Copper Oxide (CuO) Copper oxide is an example of a high-temperature superconductor that operates at above 77 K, the temperature of liquid nitrogen. It is used in advanced electrical and electronic devices.
- Lanthanum Strontium Copper Oxide (LSCO) LSCO is part of the class of high-temperature superconductors, with applications in research and electronics, including devices requiring low loss of energy.
List of Superconductors
Here’s an summary table providing more common examples of superconductors. For more information and examples, please check Stanford Advanced Materials (SAM).
Substance |
Class |
TC (K) |
HC (T) |
Type |
Al |
Element |
1.20 |
0.01 |
I |
Bi |
Element |
5.3×10⁻⁴ |
5.2×10⁻⁶ |
I |
Cd |
Element |
0.52 |
0.0028 |
I |
Diamond:B |
Element |
11.4 |
4 |
II |
Ga |
Element |
1.083 |
0.0058 |
I |
Element |
0.165 |
- |
I |
|
α-Hg |
Element |
4.15 |
0.04 |
I |
β-Hg |
Element |
3.95 |
0.04 |
I |
In |
Element |
3.4 |
0.03 |
I |
Ir |
Element |
0.14 |
0.0016 |
I |
α-La |
Element |
4.9 |
- |
I |
β-La |
Element |
6.3 |
- |
I |
Li |
Element |
4×10⁻⁴ |
- |
I |
Mo |
Element |
0.92 |
0.0096 |
I |
Element |
9.26 |
0.82 |
II |
|
Os |
Element |
0.65 |
0.007 |
I |
Pa |
Element |
1.4 |
- |
I |
Pb |
Element |
7.19 |
0.08 |
I |
Element |
2.4 |
0.03 |
I |
|
Rh |
Element |
3.25×10⁻⁴ |
4.9×10⁻⁶ |
I |
Ru |
Element |
0.49 |
0.005 |
I |
Si:B |
Element |
0.4 |
0.4 |
II |
Sn |
Element |
3.72 |
0.03 |
I |
Element |
4.48 |
0.09 |
I |
|
Tc |
Element |
7.46–11.2 |
0.04 |
II |
α-Th |
Element |
1.37 |
0.013 |
I |
Ti |
Element |
0.39 |
0.01 |
I |
Tl |
Element |
2.39 |
0.02 |
I |
α-U |
Element |
0.68 |
- |
I |
β-U |
Element |
1.8 |
- |
I |
V |
Element |
5.03 |
1 |
II |
α-W |
Element |
0.015 |
0.00012 |
I |
β-W |
Element |
1–4 |
- |
I |
Yb |
Element |
1.4 (>86 GPa) |
- |
no |
Zn |
Element |
0.855 |
0.005 |
I |
Element |
0.55 |
0.014 |
I |
|
Ba8Si46 |
Clathrate |
8.07 |
0.008 |
II |
CaH6 |
Clathrate |
215 (172 Gpa) |
- |
II |
C6Ca |
Compound |
11.5 |
0.95 |
II |
C6Li3Ca2 |
Compound |
11.15 |
- |
II |
C8K |
Compound |
0.14 |
- |
II |
C8KHg |
Compound |
1.4 |
- |
II |
C6K |
Compound |
1.5 |
- |
II |
C3K |
Compound |
3.0 |
- |
II |
C3Li |
Compound |
<0.35 |
- |
II |
C2Li |
Compound |
1.9 |
- |
II |
C3Na |
Compound |
2.3–3.8 |
- |
II |
C2Na |
Compound |
5.0 |
- |
II |
C8Rb |
Compound |
0.025 |
- |
II |
C6Sr |
Compound |
1.65 |
- |
II |
C6Yb |
Compound |
6.5 |
- |
II |
Sr2RuO4 |
Compound |
0.93 |
- |
II |
C60Cs2Rb |
Compound |
33 |
- |
II |
C60K3 |
Compound |
19.8 |
0.013 |
II |
C60RbX |
Compound |
28 |
- |
II |
C60Cs3 |
Compound |
38 |
- |
II |
FeB4 |
Compound |
2.9 |
- |
II |
InN |
Compound |
3 |
- |
II |
In2O3 |
Compound |
3.3 |
~3 |
II |
Compound |
0.45 |
- |
II |
|
MgB2 |
Compound |
39 |
74 |
II |
Nb3Al |
Compound |
18 |
- |
II |
NbC1-xNx |
Compound |
17.8 |
12 |
II |
Nb3Ge |
Compound |
23.2 |
37 |
II |
NbO |
Compound |
1.38 |
- |
II |
NbN |
Compound |
16 |
- |
II |
Nb3Sn |
Compound |
18.3 |
30 |
II |
NbTi |
Compound |
10 |
15 |
II |
SiC:B |
Compound |
1.4 |
0.008 |
I |
SiC:Al |
Compound |
1.5 |
0.04 |
II |
TiN |
Compound |
5.6 |
5 |
I |
V3Si |
Compound |
17 |
- |
II |
YB6 |
Compound |
8.4 |
- |
II |
ZrN |
Compound |
10 |
- |
I |
ZrB12 |
Compound |
6.0 |
- |
II |
Ute2 |
Compound |
2.0 |
- |
- |
[3]
Conclusion
With zero electrical resistance and unique magnetic properties, superconductors are revolutionizing fields from medical imaging to transportation. As research continues, it is likely that new materials with higher critical temperatures will be discovered, opening up even more applications.
Reference:
[1] Lebrun, Philippe & Tavian, Laurent & Vandoni, Giovanna & Wagner, U. (2002). Cryogenics for Particle Accelerators and Detectors.
[2] Yao, Chao & Ma, Yanwei. (2021). Superconducting materials: Challenges and opportunities for large-scale applications. iScience. 24. 102541. 10.1016/j.isci.2021.102541.
[3] List of superconductors. (2024, August 16). In Wikipedia. https://en.wikipedia.org/wiki/List_of_superconductors