Ni-Ti Shape Memory Alloys and Their Constituents

A Preface To Shape Memory Alloys

Shape memory alloys or SMAs are those types of alloys which always tend to ‘remember’ their original shape. This means that they remember their cold forged shapes and return to their pre-deformed or original shapes when they are heated. Some other names by which shape memory alloys are known as are memory alloys, memory metal, smart metal and smart alloys etc. SMAs are generally lightweight and are used in a number of applications. The following are some uses and applications of shape memory alloys:

1. Main Applications of SMAs

Shape memory alloys are used in several industries such as aerospace industries to make aircrafts, engines, to reduce aircraft’s noise, etc.
• These smart alloys are also used in piping, for example, water pipes, oil line pipes etc.
• Another use of shape memory alloys is in automotive industry.
• These alloys are also used in robotics, telecommunication, optometry, dentistry and medicine.
• Many engines are made using memory alloys and orthopedic surgery is another field where the can be applied.

2. Ni-Ti shape memory alloys

Ni-Ti shape memory alloys are those types of memory alloys which are made using nickel-titanium., in roughly equal amounts. Apart from these two elements, others which can be used to make shape memory alloys are copper, zinc, gold and iron but Ni-Ti is the most common memory alloy. There are many reasons for using these two elements for making smart alloys, the major ones of which are given below:

• Ni-Ti shape memory alloys are more preferable because they are stable, practical and showcase superior thermo-mechanic performance as compared to other metals.
• The yield strength of Ni-Ti based SMAs is less than that of steel but it is known that certain compositions can give a better yield than plastic and even aluminum. Infact the yield stress of Ni-Ti can go to 500 MPa.
• Using Ni-Ti based alloys can result in high level of recoverable plastic strain induced.

3. Production of Ni-Ti SMAs

Ni-Ti, or nitinol, is very difficult to create or make. This is due to the exceptionally tight compositional control that is needed and due to the exceptionally high reactivity of titanium metal. The two main melting methods used today to obtain nitinol are:

• Vacuum Arc Remelting - this is a method in which an electrical arc is striked between the raw material and the water-cooled copper strike plate. This melting procedure is done in a high vacuum. The mold used in this procedure is water-cooled copper and no carbon is introduced during the melting process.
• Vacuum induction melting - this is a method of obtaining nitinol which is performed by using alternative magnetic fields so as to heat the raw materials in a crucible . This process too is performed by high vacuum but with the only difference that carbon is introduced into the process.

There is no evidence to prove which of these methods is better than the other and both have advantages of their own.

About the author

Chin Trento

Chin Trento holds a bachelor’s degree in applied chemistry from the University of Illinois. His educational background gives him a broad base from which to approach many topics. He has been working with writing advanced materials for over four years in Stanford Advanced Materials (SAM). His main purpose in writing these articles is to provide a free, yet quality resource for readers. He welcomes feedback on typos, errors, or differences in opinion that readers come across.

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