SECTION 1. IDENTIFICATION
Product Name: Manganese(III) Fluoride
CAS #: 7783-53-1
Relevant identified uses of the substance: Scientific research and development
Supplier details:
Stanford Advanced Materials
E-mail: sales@samaterials.com
Tel: (949) 407-8904
Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.
SECTION 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)
GHS03 Flame over circle
Ox. Sol. 2
H272 May intensify fire; oxidizer.
GHS06 Skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 2 H330 Fatal if inhaled.
GHS07
Skin Irrit. 2
H315 Causes skin irritation.
Eye Irrit. 2A H319 Causes serious eye irritation.
STOT SE 3 H335 May cause respiratory irritation.
Hazards not otherwise classified
No information known.
Label elements
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS03 GHS06
Signal word
Danger
Hazard statements
H272 May intensify fire; oxidizer.
H301 Toxic if swallowed.
H330 Fatal if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P221
Take any precaution to avoid mixing with combustibles.
P301+P310
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P320
Specific treatment is urgent (see on this label).
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.
WHMIS classification
C - Oxidizing materials
D1A - Very toxic material causing immediate and serious toxic effects
D2B - Toxic material causing other toxic effects
Classification system
HMIS ratings (scale 0-4)
(Hazardous Materials Identification System)
Health (acute effects) = 3
Flammability = 3
Physical Hazard = 2
Other hazards
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical characterization: Substances
CAS# Description:
7783-53-1 Manganese(III) fluoride
Concentration:≤100%
Identification number(s):
EC number: 232-006-6
SECTION 4. FIRST AID MEASURES
Description of first aid measures
General information
Immediately remove any clothing soiled by the product.
Remove breathing apparatus only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm.
Seek immediate medical advice.
After skin contact
Immediately wash with water and soap and rinse thoroughly.
Rub in calcium gluconate solution or calcium gluconate gel immediately.
Seek immediate medical advice.
After eye contact
Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing
Do not induce vomiting; immediately call for medical help.
Information for doctor
Most important symptoms and effects, both acute and delayed
Causes skin irritation.
Causes serious eye irritation.
Fatal if inhaled.
Toxic if swallowed.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
SECTION 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing agents
Use carbon dioxide, extinguishing powder or foam. Water may be ineffective but may be used for
cooling exposed containers.
For safety reasons unsuitable extinguishing agents
Halocarbon extinguisher
Special hazards arising from the substance or mixture
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause
ignition.
If this product is involved in a fire, the following can be released:
Hydrogen fluoride (HF)
Manganese oxides
Advice for firefighters
Protective equipment:
Wear self-contained respirator.
Wear fully protective impervious suit.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.Ensure adequate ventilation
Environmental precautions:
Do not allow material to be released to the environment without proper governmental permits.
Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to section 13.
Ensure adequate ventilation.
Prevention of secondary hazards:
Acts as an oxidizing agent on organic materials such as wood, paper and fats
Keep away from combustible material.
Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1:
Substance is not listed.
PAC-2:
Substance is not listed.
PAC-3:
Substance is not listed.
SECTION 7. HANDLING AND STORAGE
Handling
Precautions for safe handling
Handle under dry protective gas.
Keep container tightly sealed.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation at the workplace.
Open and handle container with care.
Information about protection against explosions and fires:
Substance/product can reduce the ignition temperature of flammable substances.
This substance is an oxidizer and its heat of reaction with reducing agents or combustibles may cause
ignition.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
No special requirements.
Information about storage in one common storage facility:
Store away from flammable substances.
Store away from reducing agents.
Do not store with organic materials.
Store away from metal powders.
Store away from water/moisture.
Further information about storage conditions:
Store under dry inert gas.
This product is hygroscopic.
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Protect from humidity and water.
Specific end use(s)
No further relevant information available.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information about design of technical systems:
Properly operating chemical fume hood designed for hazardous chemicals and having an average
face velocity of at least 100 feet per minute.
Control parameters
Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
Additional information:
No data
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures for handling chemicals should be followed.
Keep away from foodstuffs, beverages and feed.
Remove all soiled and contaminated clothing immediately.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
Maintain an ergonomically appropriate working environment.
Breathing equipment:
Use self-contained respiratory protective device in emergency situations.
Recommended filter device for short term use:
Use a respirator with type P100 (USA) or P3 (EN 143) cartridges as a backup to engineering controls.
Risk assessment should be performed to determine if air-purifying respirators are appropriate. Only
use equipment tested and approved under appropriate government standards.
Protection of hands:
Impervious gloves
Check protective gloves prior to each use for their proper condition.
The selection of suitable gloves not only depends on the material, but also on quality. Quality will vary
from manufacturer to manufacturer.
Eye protection:
Safety glasses with side shields / NIOSH (US) or EN 166(EU)
Body protection:
Protective work clothing.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
General Information
Appearance:
Form: Crystalline
Odor: Not determined
Odor threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
Sublimation temperature / start: Not determined
Flash point: Not applicableFlammability (solid, gaseous)
Contact with combustible material may cause fire.
Ignition temperature: Not determined
Decomposition temperature: Not determined
Auto igniting: Not determined.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined
Upper: Not determined
Vapor pressure: Not applicable.
Density at 20 °C (68 °F): 3.54 g/cm³ (29.541 lbs/gal)
Relative density
Not determined.
Vapor density
Not applicable.
Evaporation rate
Not applicable.
Solubility in / Miscibility with Water: Decomposes
Partition coefficient (n-octanol/water): Not determined.
Viscosity:
dynamic: Not applicable.
kinematic: Not applicable.
Other information
No further relevant information available.
SECTION 10. STABILITY AND REACTIVITY
Reactivity
May intensify fire; oxidizer.
Chemical stability
Stable under recommended storage conditions.
Thermal decomposition / conditions to be avoided:
Decomposition will not occur if used and stored according to specifications.
Possibility of hazardous reactions
Reacts with reducing agents
Reacts with flammable substances
Conditions to avoid
No further relevant information available.
Incompatible materials:
Flammable substances
Reducing agents
Water/moisture
Organic materials
Metal powders
Hazardous decomposition products:
Hydrogen fluoride (HF)
Hydrogen fluoride
Manganese oxides
SECTION 11. TOXICOLOGICAL INFORMATIONInformation on toxicological effects
Acute toxicity:
Fatal if inhaled.
Toxic if swallowed.
The Registry of Toxic Effects of Chemical Substances (RTECS) contains acute toxicity data for this
substance.
LD/LC50 values that are relevant for classification:
Oral
LD50 86 mg/kg (mouse)
Inhalative LC50 320 mg/m3 (mouse)
Skin irritation or corrosion:
Irritant to skin and mucous membranes.
Eye irritation or corrosion:
Irritating effect.
Sensitization:
No sensitizing effects known.
Germ cell mutagenicity:
No effects known.
Carcinogenicity:
ACGIH A4: Not classifiable as a human carcinogen: Inadequate data on which to classify the agent in
terms of its carcinogenicity in humans and/or animals.
Reproductive toxicity:
No effects known.
Specific target organ system toxicity - repeated exposure:
No effects known.
Specific target organ system toxicity - single exposure:
May cause respiratory irritation.
Aspiration hazard:
No effects known.
Subacute to chronic toxicity:
The Registry of Toxic Effects of Chemical Substances (RTECS) contains multiple dose toxicity data for
this substance.
Additional toxicological information:
To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
EPA-D: Not classifiable as to human carcinogenicity: inadequate human and animal evidence of
carcinogenicity or no data are available.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity
Aquatic toxicity:
No further relevant information available.
Persistence and degradability
No further relevant information available.
Bioaccumulative potential
No further relevant information available.
Mobility in soil
No further relevant information available.
Additional ecological information:
General notes:
Do not allow material to be released to the environment without proper governmental permits.
Do not allow undiluted product or large quantities to reach ground water, water course or sewage
system.Avoid transfer into the environment.
Results of PBT and vPvB assessment
PBT:
Not applicable.
vPvB:
Not applicable.
Other adverse effects
No further relevant information available.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Recommendation
Consult state, local or national regulations to ensure proper disposal.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
SECTION 14. TRANSPORT INFORMATION
UN-Number
DOT, IMDG, IATA
UN3087
UN proper shipping name
DOT
Oxidizing solid, toxic, n.o.s. (Manganese(III) fluoride)
ADR
3087 Oxidizing solid, toxic, n.o.s. (Manganese(III) fluoride)
IMDG, IATA
OXIDIZING SOLID, TOXIC, N.O.S. (Manganese(III) fluoride)
Transport hazard class(es)
DOT
Class
5.1 Oxidizing substances
Label
5.1, 6.1
ADR
Class
5.1 (OT2) Oxidizing substances
Label
5.1+6.1
IMDG
Class
5.1 Oxidizing substances
Label
5.1/6.1
IATA
Class
5.1 Oxidizing substances
Label
5.1 (6.1)Packing group
DOT, ADR, IMDG, IATA
II
Environmental hazards:
Not applicable.
Special precautions for user
Warning: Oxidizing substances
EMS Number: F-A,S-Q
Stowage Category
B
Segregation Code
SG38 Stow "separated from" ammonium compounds.
SG49 Stow "separated from" cyanides
SG60 Stow "separated from" peroxides
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
Transport/Additional information:
DOT
Marine Pollutant (DOT):
No
UN "Model Regulation":
UN 3087 OXIDIZING SOLID, TOXIC, N.O.S. (MANGANESE(III) FLUORIDE), 5.1(6.1), II
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or mixture
GHS label elements
The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS)
Hazard pictograms
GHS03
GHS06
Signal word
Danger
Hazard statements
H272 May intensify fire; oxidizer.
H301 Toxic if swallowed.
H330 Fatal if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
P221
Take any precaution to avoid mixing with combustibles.
P301+P310
IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
P320
Specific treatment is urgent (see on this label).
P405
Store locked up.
P501
Dispose of contents/container in accordance with local/regional/national/international regulations.National regulations
All components of this product are listed in the U.S. Environmental Protection Agency Toxic
Substances Control Act Chemical substance Inventory.
All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).
SARA Section 313 (specific toxic chemical listings)
Substance is not listed.
California Proposition 65
Prop 65 - Chemicals known to cause cancer
Substance is not listed.
Prop 65 - Developmental toxicity
Substance is not listed.
Prop 65 - Developmental toxicity, female
Substance is not listed.
Prop 65 - Developmental toxicity, male
Substance is not listed.
Information about limitation of use:
For use only by technically qualified individuals.
Other regulations, limitations and prohibitive regulations
Substance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. 1907/2006.
Substance is not listed.
The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No
1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.
Substance is not listed.
Annex XIV of the REACH Regulations (requiring Authorization for use)
Substance is not listed.
Chemical safety assessment:
A Chemical Safety Assessment has not been carried out.
SECTION 16. OTHER INFORMATION
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is
believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the
properties of the product.
 Fluoride (MnF3) (CAS No. 7783-53-1).jpg)
